Genesis 2:5; Genesis 7:4; Genesis 19:24

5 Now no shrub of the field was yet in the earth, and no plant of the field had yet sprouted, for the LORD God had not sent rain upon the earth, and there was no man to cultivate the ground.

4 "For after seven more days, I will send rain on the earth forty days and forty nights; and I will blot out from the face of the land every living thing that I have made."

24 Then the LORD rained on Sodom and Gomorrah brimstone and fire from the LORD out of heaven,