Genesis 2:5; Genesis 7:4; Genesis 19:24

Genesis 2:5

5 And every plant of the field before it was in the earth, and every herb of the field before it grew: for the LORD God had not caused it to rain upon the earth, and there was not a man to till the ground.

Genesis 7:4

4 For yet seven days, and I will cause it to rain upon the earth forty days and forty nights; and every living substance that I have made will I destroy from off the face of the earth.

Genesis 19:24

24 Then the LORD rained upon Sodom and upon Gomorrah brimstone and fire from the LORD out of heaven;